Comprehensive Hydrogeological and Geochemical Study of a Brine Deposit

CLIENT

Confidential

LOCATION

Mexico

TIMEFRAME

2022-2023

Project Description

Our project involved a detailed hydrogeological and geochemical study of a brine deposit, aimed at developing a sophisticated coupled numerical model to forecast future changes in both solid and liquid reserves. This model served as a vital management tool for our client. The project included the creation of a comprehensive conceptual hydrogeological and geochemical model.

For the numerical modeling, we employed piChem, a cutting-edge code that integrated PHREEQC (for equilibrium thermodynamics) with FEFLOW (for complex groundwater flow). A key innovation in this project was the adjustment of the original piChem code to incorporate spatial mineralogical distribution in the aquifer, achieved through a cokriging exercise. This advancement enhanced the accuracy of predictions and decision-making.

Our work was recognized and selected for presentation at the international FEFLOW modeling conference, highlighting its significance and the innovative approach taken.

Scope

This study aims to quantify the reserves of both liquid (brine) and solid (precipitated salt within the storage rock of the aquifer system) phases under various scenarios for a sodium sulfate mine located in an exorheic basin in the Mexican desert. Additionally, it assesses the impact of inflowing liquid solutions—depleted in the target salt—on the mine’s reserves. The analysis is based on 50 years of exploitation data, providing a comprehensive understanding of long-term resource availability and depletion trends.

Challenges

  • Structuring and organizing a database for environmental monitoring of the mine.
  • Understanding the mine’s flow dynamics and modeling the inflow and outflow of water (considering biannual torrential rains and artificial recharge).
  • Understanding the system and thermodynamic factors influencing salt precipitation in the basin.
  • Integrated hydrogeological and geochemical modeling.
  • Development of an application for simplified scenario simulation.

Solution

Initially, historical data compilation, standardization, and critical analysis were conducted. With the validated data, a database was structured in HydroGeo Analyst software for information storage, along with queries and business intelligence reports developed for data visualization and analysis. The project then proceeded with the development of hydrogeological and hydrogeochemical conceptual models, aimed at understanding the flow in the hypersaline lagoon, the mineralogical reactivity of the reservoir rocks, and the physicochemical controls for salt precipitation and dissolution, particularly with the injection of low salt concentration solutions. The geological numerical model was developed using Leapfrog software, while the groundwater model was created in FEFLOW due to its significant flexibility in defining the numerical mesh, which allowed for better representation of the geometry and distribution of the modeled geological features. Geochemical models were developed using PHREEQC and PHREEPLOT.

Once the individual models had been calibrated with monitoring data, the spatial distribution of hydrochemical and mineralogical compositions was analyzed along the surfaces of the FEFLOW model using Surfer and ArcGIS software. This step facilitated the creation of PHREEQC models for all nodes of the model. Subsequently, the flow and transport models were coupled with the geochemical models in FEFLOW through the adaptation of the piChem plug-in.

To simulate different scenarios, an application was developed that allowed users to input desired variations in solution concentrations, injection and pumping well flow rates, as well as the inclusion and exclusion of solution inputs and outputs. The model was then updated, and the application executed the simulation. The results were automatically exported and integrated into a BI report connected to the database, enabling direct visualization of model calibration, comparison with historical data, mineral dissolution and precipitation, and the calculation of liquid and solid resources and reserves.

Results

The developed interface tool facilitated the simulation of a wide range of scenarios without the need for extensive modeling knowledge. This supported the sustainable governance of mining assets and enabled the development and visualization of alternatives geared toward optimizing ore extraction.

The phases were established in equilibrium with the physicochemical conditions of the mine and were evaluated based on their responses to the entry of different solutions, whether more or less concentrated, and how these responses impacted the resources and reserves.

Services Offered:

  • Compilation, standardization and analysis of geological, hydrological, hydrogeological, hydrochemical, mineralogical and geochemical information in a database structured in HydroGeo Analyst.
  • Revision/update of Conceptual Hydrogeological and Geochemical Models developed in other projects
  • Creation of a three-dimensional geological model in Leapfrog
  • Development of the Numerical Flow Model using Feflow® software
  • Development of the Geochemical Numerical Model using PHREEQC software
  • PHREEQC+ FEFLOW integrated numerical modeling by customizing the plug in pichem
  • Development of a user-friendly interface tool for simplified scenario simulation

Technologies Applied:

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